Banyana were undone by Desire Oparanozi's 54th minute free-kick in Limbe.
The Super Falcons booked a spot in Saturday's final alongside Cameroon, who defeated Ghana 1-0 in the earlier semi-final courtesy of Raissa Feudjio's 71st minute strike.
Nigeria beat the tournament hosts 2-0 in the 2014 final in Windhoek, Namibia.
Ghana will play South Africa on Friday for the third place as Nigeria will play Cameroon in front of a massive crowd on Saturday with the Lionesses aiming to prevent Falcons from winning and retaining the Cup.
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